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Sahay Sir > Question Answers > N Awasthi Physical Chemistry > Chapter 6 - Ionic Equilibrium (Level 1 and Level 2) > A buffer solution 0.04 M in Na2HPO4 and 0.02 in Na3PO4 is prepared. The electrolytic oxidation of 1.0 milli-mole of the organic compound RNHOH is carried out in 100 mL of the buffer. The reaction is RNHOH + H2O→RNO2+4H^+ +4e− The approximate pH of solution after the oxidation is complete is : [Given:forH3PO4,pKa1=2.2,pKa2=7.20,pKa3=12]

A buffer solution 0.04 M in Na2HPO4 and 0.02 in Na3PO4 is prepared. The electrolytic oxidation of 1.0 milli-mole of the organic compound RNHOH is carried out in 100 mL of the buffer. The reaction is RNHOH + H2O→RNO2+4H^+ +4e− The approximate pH of solution after the oxidation is complete is : [Given:forH3PO4,pKa1=2.2,pKa2=7.20,pKa3=12]

1.0 L solution is prepared by mixing 61 g benzoic acid (pKa=4.2) with 72 g of sodium benzoate and then 300 mL 1.0 M HBr solution was added. The pH of final solution is :